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No. 28 Alexei Popyrin def. No. 2 Novak Djokovic, 6-4, 6-4, 2-6, 6-4
No. 6 Andrey Rublev def. No. 32 Jiri Lehecka, 6-3, 7-5, 6-4
No. 8 Casper Ruud def. Juncheng Shang, 6-7(1), 3-6, 6-0, 6-3, 6-1
No. 9 Grigor Dimitrov def. Tallon Griekspoor, 6-3, 6-3, 6-1
No. 12 Taylor Fritz def. Francisco Comensana, 6-3, 6-4, 6-2
No. 20 Frances Tiafoe def. No. 13 Ben Shelton, 4-6, 7-5, 6-7(5), 6-4, 6-3
Brandon Nakashima def. No. 18 Lorenzo Musetti, 6-2, 3-6, 6-3, 7-6(4)
No. 3 Coco Gauff def. No. 27 Elina Svitolina, 3-6, 6-3, 6-3
No. 7 Qinwen Zheng def. Jule Niemeier, 6-2, 6-1
No. 13 Emma Navarro def. No. 19 Marta Kostyuk, 6-4, 4-6, 6-3
No. 33 Elise Mertens def. No. 14 Madison Keys, 6-7(5), 7-5, 6-4
Yafan Wang def. No. 20 Victoria Azarenka, 6-4, 3-6, 6-1
No. 24 Donna Vekic def. Peyton Stearns, 7-5, 6-4
No. 26 Paula Badosa def. Elena Gabriela Ruse, 4-6, 6-1, 7-6(8)
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